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991.
分别以硫酸/水和高氯酸锂/乙腈为电解质溶液, 采用循环伏安法在铂基底电极上电聚合制备了聚吡咯, 研究了电解质溶液对聚吡咯电聚合过程中过氧化行为的影响. 与硫酸/水溶液相比, 在高氯酸锂/乙腈溶液中电聚合制备的聚吡咯发生过氧化的峰电位正移了0.42 V. 采用原位傅里叶变换红外(in situ FTIR)光谱技术检测, 结果表明, 电聚合制备的聚吡咯在2种电解质溶液中均发生了过氧化反应, 其β-C经氧化生成C-OH或CO. 在硫酸/水溶液中, 部分聚吡咯发生电氧化降解生成CO2, 致使其共轭结构被破坏, 电导率迅速下降. 而在高氯酸锂/乙腈溶液中, 在更高的电位范围内, 聚吡咯并没有氧化降解成CO2. 相似文献
992.
Dynamic analysis of axially moving thermally loaded two-dimensional system is presented in this paper. Using the Hamilton's principle, the differential equation of the transverse motion of the moving plate is derived. Using the extended Galerkin method the approximate solution is determined in this work. To verify the present approach, the calculation results of buckling thermal load for stationary plate are compared with the results published in literature. Dynamic analysis of axially moving aluminum plate subjected to thermal loading is presented. Besides the thermal critical loading the effects of transport speed and axial tension on dynamic behavior of axially moving aluminum plate are presented. 相似文献
993.
开展了水相中硫脲与碘代芳烃反应生成芳基硫醚衍生物的微波辅助合成研究。 高效地合成了一系列的芳基硫醚衍生物,最高收率达到90%。 相似文献
994.
为了使解由非0非1型逻辑方程构成的逻辑方程组灵活多样化,给出了逻辑方程组成立的充要条件,化逻辑方程组为0型或1型逻辑方程的方法,并给予证明,得到了若两个0型逻辑方程的解集分别为X1、X2,则逻辑方程组的解集为X1+X2;若两个1型逻辑方程的解集分别为X3、X4,则逻辑方程组的解集为X3+X4的结论,从而可应用结论解非0非1型逻辑方程构成的逻辑方程组. 相似文献
995.
K. Rameshbabu P. Kannan M. Gunasekaran P. Srinivasan R. Ramesh Babu R. Gopalakrishnan P. Ramasamy 《Crystal Research and Technology》2006,41(7):718-722
4,4′‐dihydroxy‐α‐methylstilbene (DHAMS) was synthesized by condensation reaction with chloroacetone and phenol in the presence of concentrated sulfuric acid, and has been successfully grown by solution growth technique. This is the first report in the literature on the crystallization of DHAMS and exhibited the birefringent melt (liquid crystal property) of the optical properties. FTIR and FTNMR studies are in accordance with the structure. Good quality crystals were grown by slow evaporation technique by acetone as solvent. A transmission spectrum of the crystal was obtained in the region of 285 nm. The structural and optical properties were studied. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
996.
A series of ionic complexes of 1,8–bis(dimethylamino)naphthalene with selected inorganic acids such as HCl, HBr, HI, HSCN and HBF4 were synthesised and thoroughly investigated by means of powder diffractometry and analytical methods. The crystallographic data for these compounds as well as the results of the structure solution by powder diffraction methods of the 1,8–bis(dimethylamino)naphthalene.HI complex, which crystallizes in the monoclinic system, S.G. P21/c (14), a=7.999(2)Å, b=23.053(3)Å, c=7.948(1)Å, β=99.63°, RF=17.1%, Rwp=15.5%, are discussed and presented in this work. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
997.
ZHU Jia-Min MA Zheng-Yi 《理论物理通讯》2006,46(3):393-396
In this paper, using the variable coefficient generalized projected Rieatti equation expansion method, we present explicit solutions of the (2+1)-dimensional variable coefficients Broer-Kaup (VCBK) equations. These solutions include Weierstrass function solution, solitary wave solutions, soliton-like solutions and trigonometric function solutions. Among these solutions, some are found for the first time. Because of the three or four arbitrary functions, rich localized excitations can be found. 相似文献
998.
ZHENG Chun-Long YE Jian-Feng XU Yuan 《理论物理通讯》2006,46(3):461-466
Using a special Painleve-Baecklund transformation as well as the extended mapping approach and the linear superposition theorem, we obtain new families of variable separation solutions to the (2+1)-dimensional generalized Broer-Kaup (GBK) system. Based on the derived exact solution, we reveal some novel evolutional behaviors of localized excitations, i.e. fission and fusion phenomena in the (2+1)-dimensional GBK system. 相似文献
999.
Conditional Symmetries and Solutions to a Class of Nonlinear Diffusion-Convection Equations 总被引:1,自引:0,他引:1
JI Li-Na QU Chang-Zheng 《理论物理通讯》2006,46(4):668-674
The present paper discusses a class of nonlinear diffusion-convection equations with source. The method that we use is the conditional symmetry method. It is shown that the equation admits certain conditional symmetries for coefficient functions of the equations. As a consequence, solutions to the resulting equations are obtained. 相似文献
1000.
In this paper, new Jacobi elliptic function solutions of
multi-component mKdV equation are obtained directly in a unified
way. When the modulus m→1, those periodic solutions
degenerate as the corresponding hyperbolic function solutions.
Then, to the three-component mKdV equation, five types of
effective solution are presented in detail. 相似文献